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The Fluoride‐Free Transmetalation of Organosilanes to Gold
Author(s) -
Dupuy Stéphanie,
Slawin Alexandra M. Z.,
Nolan Steven P.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202299
Subject(s) - transmetalation , reagent , silane , fluoride , aryl , chemistry , combinatorial chemistry , organic chemistry , polymer chemistry , catalysis , inorganic chemistry , alkyl
Golden transfer : The versatile gold(I) complex [Au(IPr)(OH)] permits very straightforward access to a series of aryl‐, vinyl‐ and alkylgold silanolates by reaction with the appropriate silane reagent. These silanolate compounds are key intermediates in a fluoride‐free process that results in the net transmetalation of organosilanes to gold.