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Supramolecular Approach by Using Jahn–Teller Sites to Construct a {Mn 13 }‐Based Coordination Polymer and Modify its Magnetic Properties
Author(s) -
Zhang Lei,
Clérac Rodolphe,
Onet Camelia I.,
Venkatesan Munuswamy,
Heijboer Pierre,
Schmitt Wolfgang
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202297
Subject(s) - supramolecular chemistry , tetracyanoquinodimethane , construct (python library) , jahn–teller effect , unit (ring theory) , computer science , coordination complex , coordination polymer , materials science , chemistry , combinatorial chemistry , crystallography , nanotechnology , molecule , crystal structure , mathematics , ion , organic chemistry , mathematics education , programming language , metal
Put a spin on it : A {Mn 13 } coordination cluster has been used as a secondary building unit for the preparation of an open‐framework structure for which the magnetic properties can be modified by solution adsorption of tetracyanoquinodimethane radical anions (TCNQ .− ; see figure). The applied supramolecular approach takes advantage of kinetically labile Jahn–Teller sites and can be generalised for the construction and post‐synthetic modification of multifunctional materials.