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The Insertion of Terminal Phosphinidene Complexes into the BH Bond of Amine and Phosphine Boranes
Author(s) -
Tian Rongqiang,
Mathey François
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202277
Subject(s) - phosphinidene , phosphine , chemistry , electrophile , boranes , nucleophile , amine gas treating , terminal (telecommunication) , boron , medicinal chemistry , stereochemistry , organic chemistry , catalysis , telecommunications , computer science
Push–pull complexation : Transient terminal phosphinidene complexes [RPW(CO) 5 ] insert at 110 °C into the BH bonds of LBH 3 (L = Et 3 N, Ph 3 P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus.