Iron‐Catalyzed CH Hydroxylation and Olefin  cis ‐Dihydroxylation Using a Single‐Electron Oxidant and Water as the Oxygen‐Atom Source | Zendy

GarciaBosch Isaac | Zendy; Codolà Zoel | Zendy; Prat Irene | Zendy; Ribas Xavi | Zendy; LloretFillol Julio | Zendy; Costas Miquel | Zendy

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Iron‐Catalyzed CH Hydroxylation and Olefin cis ‐Dihydroxylation Using a Single‐Electron Oxidant and Water as the Oxygen‐Atom Source

Author(s) -

GarciaBosch Isaac,

Codolà Zoel,

Prat Irene,

Ribas Xavi,

LloretFillol Julio,

Costas Miquel

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201202147

Subject(s) - dihydroxylation , hydroxylation , cerium , catalysis , chemistry , oxygen atom , olefin fiber , medicinal chemistry , organic chemistry , molecule , enantioselective synthesis , enzyme

Bioinspired oxidation : The hydroxylation of alkanes with retention of the configuration and the cis ‐dihydroxylation of olefins can be accomplished using [Fe II (CF 3 SO 3 ) 2 ( Me,H PyTACN)] ( 1 ) as a catalyst, water as an oxygen‐atom source, and cerium ammonium nitrate (CAN) as a single‐electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [Fe IV (O)(OH 2 )( Me,H PyTACN)] + .

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