Neutral 1,3‐Diindolylureas for Nerve Agent Remediation | Zendy

BarbaBon Andrea | Zendy; Costero Ana M. | Zendy; Parra Margarita | Zendy; Gil Salvador | Zendy; MartínezMáñez Ramón | Zendy; Sancenón Félix | Zendy; Gale Philip A. | Zendy; Hiscock Jennifer R. | Zendy

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Neutral 1,3‐Diindolylureas for Nerve Agent Remediation

Author(s) -

BarbaBon Andrea,

Costero Ana M.,

Parra Margarita,

Gil Salvador,

MartínezMáñez Ramón,

Sancenón Félix,

Gale Philip A.,

Hiscock Jennifer R.

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201202028

Subject(s) - nerve agent , scheme (mathematics) , environmental remediation , hydrolysis , mechanism (biology) , quality (philosophy) , chemistry , computer science , combinatorial chemistry , philosophy , organic chemistry , mathematics , biology , epistemology , mathematical analysis , ecology , contamination , acetylcholinesterase , enzyme

Efficient neutralization of nerve‐agent simulants by 1,3‐diindolylureas in a neutral medium was investigated (see scheme; DCP=diethylchlorophosphate, DCNP=diethylcyanophosphonate). The rate of hydrolysis of the simulants was found to increase by as much as 45 % in the presence of these compounds. A mechanism based on the simulant complexation was established.

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