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Solid‐State 73 Ge NMR Spectroscopy of Simple Organogermanes
Author(s) -
Hanson Margaret A.,
Sutrisno Andre,
Terskikh Victor V.,
Baines Kim M.,
Huang Yining
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201201944
Subject(s) - nuclear magnetic resonance spectroscopy , nuclear magnetic resonance crystallography , germanium , spectroscopy , solid state nuclear magnetic resonance , carbon 13 nmr satellite , simple (philosophy) , fluorine 19 nmr , transverse relaxation optimized spectroscopy , materials science , crystallography , nuclear magnetic resonance , chemistry , physics , silicon , quantum mechanics , optoelectronics , philosophy , epistemology
Germanium‐73 is an extremely challenging nucleus to examine by NMR spectroscopy due to its unfavorable NMR properties. Through the use of an ultrahigh (21.1 T) magnetic field, a systematic study of a series of simple organogermanes was carried out. In those cases for which X‐ray structural data were available, correlations were drawn between the NMR parameters and structural metrics. These data were combined with DFT calculations to obtain insight into the structures of several compounds with unknown crystal structures.