Coupling of Two Multistep Catalytic Cycles for the One‐Pot Synthesis of Propargylamines from Alcohols and Primary Amines on a Nanoparticulated Gold Catalyst | Zendy

Corma Avelino | Zendy; Navas Javier | Zendy; Sabater María J. | Zendy

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Coupling of Two Multistep Catalytic Cycles for the One‐Pot Synthesis of Propargylamines from Alcohols and Primary Amines on a Nanoparticulated Gold Catalyst

Author(s) -

Corma Avelino,

Navas Javier,

Sabater María J.

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201837

Subject(s) - catalysis , amine gas treating , primary (astronomy) , coupling (piping) , coupling reaction , chemistry , catalytic cycle , combinatorial chemistry , colloidal gold , alcohol , materials science , organic chemistry , nanotechnology , nanoparticle , metallurgy , physics , astronomy

A one‐pot reaction was performed with a nanoparticulated gold catalyst. A secondary amine is formed through N‐monoalkylation of a primary amine with an alcohol by a borrowing hydrogen methodology in a three‐step reaction. The secondary amine formed enters into a second A 3 ‐coupling cycle to give propargylamines. The multistep reaction requires a gold species formed and stabilized on a ceria surface.

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