A New Mode of Activation of CO 2  by Metal–Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature | Zendy

Vogt Matthias | Zendy; Gargir Moti | Zendy; Iron Mark A. | Zendy; DiskinPosner Yael | Zendy; BenDavid Yehoshoa | Zendy; Milstein David | Zendy

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A New Mode of Activation of CO 2 by Metal–Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature

Author(s) -

Vogt Matthias,

Gargir Moti,

Iron Mark A.,

DiskinPosner Yael,

BenDavid Yehoshoa,

Milstein David

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201730

Subject(s) - ruthenium , ligand (biochemistry) , pincer movement , chemistry , metal , atom (system on chip) , mode (computer interface) , pincer ligand , combinatorial chemistry , computer science , stereochemistry , organic chemistry , catalysis , biochemistry , receptor , embedded system , operating system

Team work : Although CO 2 binding to metal centers usually involves π coordination to a CO group or σ bonds to the carbon or oxygen atom of the CO 2 molecule, a new mode of metal–ligand cooperative activation of CO 2 to a ruthenium PNP pincer complex involving aromatization/dearomatization steps is presented in experimental and theoretical studies (see scheme).

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