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Triazole‐Based One‐Dimensional Spin‐Crossover Coordination Polymers
Author(s) -
Roubeau Olivier
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201201647
Subject(s) - spin crossover , crossover , polymer , coordination polymer , materials science , nanotechnology , particle (ecology) , crystallography , chemistry , computer science , composite material , oceanography , artificial intelligence , geology
One‐dimensional coordination Fe II polymers constructed through triple N 1 , N 2 ‐1,2,4‐triazole bridges form a unique class of spin‐crossover materials, the synthetic versatility of which allows tuning the spin‐crossover properties, the design of gels, films, liquid crystals, and nanoparticles and single‐particle addressing. This Minireview provides the first complete overview of these very attractive switchable materials and their most recent developments.