Catalytic Enantioselective  tert ‐Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5‐Hydrogen Transfer | Zendy

Chen Liujuan | Zendy; Zhang Long | Zendy; Lv Jian | Zendy; Cheng JinPei | Zendy; Luo Sanzhong | Zendy

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Catalytic Enantioselective tert ‐Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5‐Hydrogen Transfer

Author(s) -

Chen Liujuan,

Zhang Long,

Lv Jian,

Cheng JinPei,

Luo Sanzhong

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201532

Subject(s) - stereospecificity , enantioselective synthesis , catalysis , scope (computer science) , substrate (aquarium) , chemistry , binary number , combinatorial chemistry , stereochemistry , computer science , organic chemistry , mathematics , arithmetic , biology , ecology , programming language

Selective H transfer by ABC : A new asymmetric binary acid catalyst was developed to promote 1,5‐H transfer specifically and stereoselectively in tert ‐aminocyclization reactions with excellent activity, high enantioselectivity, and broad substrate scope. The H atom (in red) was proven to transfer through a stereospecific suprafacial pathway (see scheme).

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