Deoxygenation of Coordinated Oxaphosphiranes: A New Route to PC Double‐Bond Systems | Zendy

Albrecht Carolin | Zendy; Shi Lili | Zendy; Pérez Janaina Marinas | Zendy; van Gastel Maurice | Zendy; Schwieger Sebastian | Zendy; Neese Frank | Zendy; Streubel Rainer | Zendy

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Deoxygenation of Coordinated Oxaphosphiranes: A New Route to PC Double‐Bond Systems

Author(s) -

Albrecht Carolin,

Shi Lili,

Pérez Janaina Marinas,

van Gastel Maurice,

Schwieger Sebastian,

Neese Frank,

Streubel Rainer

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201405

Subject(s) - deoxygenation , double bond , bond , chemistry , stereochemistry , business , polymer chemistry , organic chemistry , catalysis , finance

Phosphaalkenes : Deoxygenation of oxaphosphirane complexes 1 and 2 by using Ti III complexes gave mixtures of E / Z phosphaalkene complexes 3 a , b and 4 a , b . Theoretical calculations of deoxygenation pathways of 1 revealed that the final products are obtained via intermediate 5 providing the final products by reaction with a second [TiCpCl 2 ] unit and CO bond cleavage (see scheme).

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