TRANSDIP: A  trans ‐Chelating Ligand Tailor‐Made for Probing Unusual Pd 0  and Pd II  Intermediates | Zendy

GramageDoria Rafael | Zendy; Armspach Dominique | Zendy; Matt Dominique | Zendy; Toupet Loic | Zendy

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TRANSDIP: A trans ‐Chelating Ligand Tailor‐Made for Probing Unusual Pd 0 and Pd II Intermediates

Author(s) -

GramageDoria Rafael,

Armspach Dominique,

Matt Dominique,

Toupet Loic

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201403

Subject(s) - diphosphines , chelation , ligand (biochemistry) , palladium , carbon fibers , chemistry , stereochemistry , crystallography , combinatorial chemistry , computer science , organic chemistry , catalysis , algorithm , biochemistry , receptor , composite number

Forty years after Venanzi's seminal studies on trans ‐spanning diphosphines, a cavity‐shaped trans chelator (TRANSDIP) has been used to monitor the stepwise formation of a carbon–carbon bond on a palladium centre. Furthermore, the ligand, which incorporates a cyclodextrin subunit, enabled the synthesis of the first η 2 ‐dioxygen complex in which the M–O 2 unit is entrapped within a cavity (see figure).

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