A Samarium “Soluble” Anode: A New Source of SmI 2  Reagent for Electrosynthetic Application | Zendy

Sahloul Kamar | Zendy; Sun Linhao | Zendy; Requet Alexandre | Zendy; Chahine Youhana | Zendy; Mellah Mohamed | Zendy

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A Samarium “Soluble” Anode: A New Source of SmI 2 Reagent for Electrosynthetic Application

Author(s) -

Sahloul Kamar,

Sun Linhao,

Requet Alexandre,

Chahine Youhana,

Mellah Mohamed

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201390

Subject(s) - samarium , electrosynthesis , reagent , electrolysis , anode , electrochemistry , solvent , chemistry , combinatorial chemistry , computer science , organic chemistry , electrode , electrolyte

An electrochemical method to prepare solutions of samarium diiodide in THF is reported. The simple electrolysis of a samarium rod provides a rapid and straightforward in situ synthesis of SmI 2 . The electrogenerated complex catalyzes various CC bond formations. The reagent is produced continuously (see scheme) and leads to efficient organic electrosynthesis with significantly smaller amounts of solvent than usually required.

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