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Metal–Metal Interaction and Flexible Motion of Triple‐Decker Polypyridyl Platinum(II) and Palladium(II) Complexes
Author(s) -
Kajitani Yuta,
Tsuge Kiyoshi,
Sasaki Yoichi,
Kato Masako
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201201274
Subject(s) - palladium , platinum , metal , chemistry , materials science , polymer chemistry , metallurgy , catalysis , organic chemistry
Triple‐decker polypyridyl platinum(II) and palladium(II) complexes were prepared using an N,S‐bridging ligand. In solution, tight stacking structures were observed at low temperatures, whereas flexible motion was observed at room temperature. These dynamic behaviors are reflected in the electronic absorption and NMR spectra of these complexes (see scheme).