Facile Synthesis of  meso ‐Arylamino‐ and Alkylaminosubporphyrins | Zendy

Kitano Masaaki | Zendy; Hayashi Shinya | Zendy; Tanaka Takayuki | Zendy; Aratani Naoki | Zendy; Osuka Atsuhiro | Zendy

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Facile Synthesis of meso ‐Arylamino‐ and Alkylaminosubporphyrins

Author(s) -

Kitano Masaaki,

Hayashi Shinya,

Tanaka Takayuki,

Aratani Naoki,

Osuka Atsuhiro

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201256

Subject(s) - heteroatom , position (finance) , scheme (mathematics) , computer science , content (measure theory) , information retrieval , chemistry , business , organic chemistry , mathematics , ring (chemistry) , mathematical analysis , finance

Newcomers : meso ‐Arylamino‐ and meso ‐alkylaminosubporphyrins have been synthesized by the Pd‐catalyzed aminations of meso ‐bromosubporphyrin 1 as the first example of subporphyrins containing heteroatom substituents at the meso ‐position. The X‐ray structural analyses have revealed significant structural distortions of meso ‐aminosubporphyrins 2 due to the effective electronic interaction (see scheme).

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