Selective Synthesis and Derivatization of Alkali Metal Silanides MSi(SiH 3 ) 3 | Zendy

Stueger Harald | Zendy; Mitterfellner Thomas | Zendy; Fischer Roland | Zendy; Walkner Christoph | Zendy; Patz Matthias | Zendy; Wieber Stephan | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Selective Synthesis and Derivatization of Alkali Metal Silanides MSi(SiH 3 ) 3

Author(s) -

Stueger Harald,

Mitterfellner Thomas,

Fischer Roland,

Walkner Christoph,

Patz Matthias,

Wieber Stephan

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201253

Subject(s) - derivatization , alkali metal , silicon , simple (philosophy) , inorganic chemistry , metal , chemistry , materials science , organic chemistry , high performance liquid chromatography , philosophy , epistemology

Greetings from silicon valley : Alkali metal silanides (H 3 Si) 3 Si − M + were shown to be selectively accessible for the first time by the reaction of neopentasilane Si(SiH 3 ) 4 with t BuOM or i Pr 2 NLi. The method allows the convenient derivatization of higher silicon hydrides and provides a simple access for unprecedented systematic studies on the chemical behavior of hydropolysilanes (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research