Transition Metal and Hydrogen Bond Donor Hybrids: Catalysts for the Activation of Alkylidene Malonates | Zendy

Nickerson David M. | Zendy; Mattson Anita E. | Zendy

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Transition Metal and Hydrogen Bond Donor Hybrids: Catalysts for the Activation of Alkylidene Malonates

Author(s) -

Nickerson David M.,

Mattson Anita E.

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201206

Subject(s) - urea , thiourea , palladium , catalysis , nucleophile , chemistry , yield (engineering) , transition metal , reactivity (psychology) , combinatorial chemistry , organic chemistry , medicinal chemistry , materials science , medicine , alternative medicine , pathology , metallurgy

Palladium ureaka ! Urea palladacycles are introduced to activate alkylidene malonates for nucleophilic attack. The strategic incorporation of palladium on a urea scaffold give rise to urea catalysts with enhanced reactivity when compared to conventional urea and thiourea catalysts. A variety of alkylidene malonates are easily activated with urea palladacycle catalysts giving rise to the corresponding products in high yield (see scheme).

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