Synthesis and STM Imaging of Symmetric and Dissymmetric Ethynyl‐Bridged Dimers of Boron–Subphthalocyanine Bowl‐Shaped Nanowheels | Zendy

Jacquot de Rouville HenriPierre | Zendy; Garbage Romain | Zendy; Ample Francisco | Zendy; Nickel Anja | Zendy; Meyer Joerg | Zendy; Moresco Francesca | Zendy; Joachim Christian | Zendy; Rapenne Gwénaël | Zendy

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Synthesis and STM Imaging of Symmetric and Dissymmetric Ethynyl‐Bridged Dimers of Boron–Subphthalocyanine Bowl‐Shaped Nanowheels

Author(s) -

Jacquot de Rouville HenriPierre,

Garbage Romain,

Ample Francisco,

Nickel Anja,

Meyer Joerg,

Moresco Francesca,

Joachim Christian,

Rapenne Gwénaël

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201201123

Subject(s) - boron , chemistry , class (philosophy) , crystallography , nanotechnology , materials science , computer science , organic chemistry , artificial intelligence

The future's wheel : A new class of wheels, based on subphthalocyanine fragments, for future incorporation in functional nanovehicles is reported (see figure). The syntheses of a symmetric wheel, a nitrogen‐tagged wheel, and their ethynyl‐bridged homodimers are presented. Theoretical calculations and STM imaging demonstrate the advantage of a bowl‐shaped structure and the efficiency of the tag for STM imaging.

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