Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non‐Heme Iron Catalysts | Zendy

Wang Bin | Zendy; Wang Shoufeng | Zendy; Xia Chungu | Zendy; Sun Wei | Zendy

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Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non‐Heme Iron Catalysts

Author(s) -

Wang Bin,

Wang Shoufeng,

Xia Chungu,

Sun Wei

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201200992

Subject(s) - enantioselective synthesis , catalysis , benzimidazole , enantiomer , combinatorial chemistry , chemistry , heme , enantiomeric excess , proline , organic chemistry , amino acid , biochemistry , enzyme

Iron(II) efficiency : The iron complexes of N 4 ligands, derived from proline and benzimidazole, exhibited an unprecedented activity and enantioselectivity for the epoxidation of a variety of di‐ and trisubstituted enones (see scheme). This system, based on synthetic non‐heme iron catalysts, provides ready access to a wide range of epoxyketones of high enantiomeric purity.

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