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Tuning the Electronic and Spin Complexity in Organic–Inorganic Molecular Hybrid Compounds
Author(s) -
Rabeah Jabor,
Stößer Reinhard,
Jiao Haijun,
Troyanov Sergey I.,
Radnik Jörg,
Dwelk Helmut,
Meisel Manfred,
Brückner Angelika
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200931
Subject(s) - phosphonate , vanadium , cage , simple (philosophy) , ligand (biochemistry) , charge (physics) , spin crossover , combinatorial chemistry , chemistry , nanotechnology , materials science , computer science , crystallography , inorganic chemistry , physics , organic chemistry , combinatorics , quantum mechanics , philosophy , mathematics , biochemistry , receptor , epistemology
Caught by the cage : New vanadium phosphonate cages with a fluoride template inside and charge‐compensating transition‐metal cations outside were prepared in a simple way. The charge and ligand sphere of the cation govern its interaction with the cage and can be used to modify the magnetic and redox properties of the cage, which also depend on the anionic template (see figure).