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Tetrakis(phthalocyaninato) Rare‐Earth–Cadmium–Rare‐Earth Quadruple‐Decker Sandwich SMMs: Suppression of QTM by Long‐Distance f–f Interactions
Author(s) -
Wang Hailong,
Liu Tao,
Wang Kang,
Duan Chunying,
Jiang Jianzhuang
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200552
Subject(s) - isostructural , rare earth , intramolecular force , chemistry , quantum tunnelling , magnetization , crystallography , cadmium , condensed matter physics , stereochemistry , physics , magnetic field , mineralogy , crystal structure , quantum mechanics , organic chemistry
Long‐distance f–f interactions : Systematic and comparative studies of the magnetic properties of a series of isostructural sandwich‐type tetrakis(phthalocyaninato) diterbium and monoterbium quadruple‐decker complexes clearly reveal the suppression of the quantum tunneling of magnetization by the long‐distance intramolecular f–f interactions (see figure).