Tetrakis(phthalocyaninato) Rare‐Earth–Cadmium–Rare‐Earth Quadruple‐Decker Sandwich SMMs: Suppression of QTM by Long‐Distance f–f Interactions | Zendy

Wang Hailong | Zendy; Liu Tao | Zendy; Wang Kang | Zendy; Duan Chunying | Zendy; Jiang Jianzhuang | Zendy

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Tetrakis(phthalocyaninato) Rare‐Earth–Cadmium–Rare‐Earth Quadruple‐Decker Sandwich SMMs: Suppression of QTM by Long‐Distance f–f Interactions

Author(s) -

Wang Hailong,

Liu Tao,

Wang Kang,

Duan Chunying,

Jiang Jianzhuang

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201200552

Subject(s) - isostructural , rare earth , intramolecular force , chemistry , quantum tunnelling , magnetization , crystallography , cadmium , condensed matter physics , stereochemistry , physics , magnetic field , mineralogy , crystal structure , quantum mechanics , organic chemistry

Long‐distance f–f interactions : Systematic and comparative studies of the magnetic properties of a series of isostructural sandwich‐type tetrakis(phthalocyaninato) diterbium and monoterbium quadruple‐decker complexes clearly reveal the suppression of the quantum tunneling of magnetization by the long‐distance intramolecular f–f interactions (see figure).

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