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Synthesis of Uranium Materials under Extreme Conditions: UO 2 [B 3 Al 4 O 11 (OH)], a Complex 3D Aluminoborate
Author(s) -
Wu Shijun,
Beermann Oliver,
Wang Shuao,
Holzheid Astrid,
Depmeier Wulf,
Malcherek Thomas,
Modolo Giuseppe,
Alekseev Evgeny V.,
AlbrechtSchmitt Thomas E.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200505
Subject(s) - actinide , uranium , thermal stability , phase (matter) , uranium dioxide , chemistry , materials science , radiochemistry , inorganic chemistry , metallurgy , organic chemistry
Extreme synthesis : High‐temperature/high‐pressure synthetic methods have been used to prepare the first actinide aluminoborate, UO 2 [B 3 Al 4 O 11 (OH)]. This material displays rich coordination chemistry and remarkable thermal stability despite being a hydrous phase.