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Controlling State of Breathing of Two Isoreticular Microporous Metal–Organic Frameworks with Triazole Homologues
Author(s) -
Jiang ZhiQiang,
Jiang GuiYuan,
Wang Fei,
Zhao Zhen,
Zhang Jian
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200385
Subject(s) - microporous material , triazole , benzotriazole , chemistry , state (computer science) , breathing , metal organic framework , computer science , organic chemistry , psychology , programming language , psychiatry , adsorption
Breathing effect : Using two triazole homologues (1 H ‐benzotriazole and 1,2,3‐1 H ‐triazole), two isoreticular microporous Zn–benzenedicarboxylate frameworks 1 and 2 with reverse dynamic features are presented, in which different sized triazole ligands effectively control the state of breathing of two flexible frameworks (see figure).