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Sequestering Aromatic Molecules with a Spin‐Crossover Fe II Microporous Coordination Polymer
Author(s) -
MuñozLara Francisco J.,
Gaspar Ana B.,
Muñoz M. Carmen,
Arai Masashi,
Kitagawa Susumu,
Ohba Masaaki,
Real José Antonio
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200377
Subject(s) - spin crossover , microporous material , naphthalene , molecule , polymer , coordination polymer , anthracene , chemistry , crystallography , aromaticity , phenazine , materials science , polymer chemistry , photochemistry , organic chemistry
All in a spin : A series of three‐dimensional porous coordination polymer {Fe(dpe)[Pt(CN) 4 ]}⋅G (dpe=1,2‐di(4‐pyridyl)ethylene; G=phenazine, anthracene, or naphthalene) exhibiting spin crossover and host–guest functions is reported. The magnetic properties of the framework are very sensitive to the chemical nature (aromatic or hydroxilic solvents) and the size of the included guest molecules.