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A New “Fully Reduced” Polyoxovanadate Constructed from Nanosized Triangle‐Shaped [V III 3 V IV 18 P 6 O 60 (DACH) 3 ]} 9− Cluster Anions Exhibiting Ferrimagnetic Interactions
Author(s) -
Wang CongLing,
Zhang Zhibin,
Fu Jie,
Xu Yan,
Zhu Dunru
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200261
Subject(s) - ferrimagnetism , vanadium , hydrothermal circulation , cluster (spacecraft) , styrene , crystallography , chemistry , selectivity , catalysis , inorganic chemistry , materials science , nuclear chemistry , physics , nuclear magnetic resonance , chemical engineering , magnetic field , magnetization , polymer , organic chemistry , quantum mechanics , computer science , engineering , copolymer , programming language
Magnetic personality : A pentavalent vanadium source was employed to prepare the largest highly reduced polyoxovanadate cluster by virtue of the reducing power of 1,2‐diaminocyclohexane under hydrothermal conditions. The new non‐classical triangle‐shaped cluster shows good catalytic selectivity for the oxidation of styrene and exhibits ferrimagnetic interactions that could make it a promising magnetic material.