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Large Increase of the Lifetime of a Charge‐Separated State in a Molecular Triad Induced by Hydrogen‐Bonding Solvent
Author(s) -
Hankache Jihane,
Wenger Oliver S.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200199
Subject(s) - triad (sociology) , solvent , charge (physics) , hydrogen bond , state (computer science) , chemistry , hydrogen , molecule , photochemistry , computer science , materials science , crystallography , organic chemistry , physics , psychology , algorithm , particle physics , psychoanalysis
Life of triad : The lifetime of a charge‐separated state (see figure) increases from about 50 to 2000 ns when the solvent is changed from aprotic CH 2 Cl 2 to the strong hydrogen‐bond donor hexafluoroisopropanol.