Mn II –Gd III  Phosphonate Cages with a Large Magnetocaloric Effect | Zendy

Zheng YanZhen | Zendy; Pineda Eufemio Moreno | Zendy; Helliwell Madeleine | Zendy; Winpenny Richard E. P. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Mn II –Gd III Phosphonate Cages with a Large Magnetocaloric Effect

Author(s) -

Zheng YanZhen,

Pineda Eufemio Moreno,

Helliwell Madeleine,

Winpenny Richard E. P.

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201200152

Subject(s) - magnetic refrigeration , phosphonate , manganese , antiferromagnetism , lanthanide , crystallography , entropy (arrow of time) , chemistry , materials science , condensed matter physics , physics , thermodynamics , magnetization , organic chemistry , quantum mechanics , ion , magnetic field

Cool cages! The use of phosphonates has led to formation of a family of manganese(II)–lanthanide(III) heterometallic cages with structurally beautiful cores (see figure). Magnetic studies show antiferromagnetic interactions within the manganese centers and huge entropy change in the {Mn 4 Gd 6 } complex, which, in principle, can be used for ultralow temperature cooling.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research