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Chlorine‐Induced Assembly of a Cationic Coordination Cage with a μ 5 ‐Carbonato‐Bridged Mn II 24 Core
Author(s) -
Xiong KeCai,
Jiang FeiLong,
Gai YanLi,
Yuan DaQiang,
Han Dong,
Ma Jie,
Zhang ShuQuan,
Hong MaoChun
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201200125
Subject(s) - cationic polymerization , chlorine , octahedron , crystallography , chemistry , core (optical fiber) , chlorine atom , manganese , crystal structure , stereochemistry , inorganic chemistry , materials science , polymer chemistry , medicinal chemistry , organic chemistry , composite material
Chlorine caged in! The chlorine‐induced assembly of six shuttlecock‐like tetranuclear Mn II building blocks generated in situ based on p ‐ tert ‐butylthiacalix[4]arene and facial anions gave rise to a novel truncated distorted octahedral cationic coordination cage with a μ 5 ‐carbonato‐bridged Mn II 24 core (see figure).