Chlorine‐Induced Assembly of a Cationic Coordination Cage with a μ 5 ‐Carbonato‐Bridged Mn II  24  Core | Zendy

Xiong KeCai | Zendy; Jiang FeiLong | Zendy; Gai YanLi | Zendy; Yuan DaQiang | Zendy; Han Dong | Zendy; Ma Jie | Zendy; Zhang ShuQuan | Zendy; Hong MaoChun | Zendy

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Chlorine‐Induced Assembly of a Cationic Coordination Cage with a μ 5 ‐Carbonato‐Bridged Mn II 24 Core

Author(s) -

Xiong KeCai,

Jiang FeiLong,

Gai YanLi,

Yuan DaQiang,

Han Dong,

Ma Jie,

Zhang ShuQuan,

Hong MaoChun

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201200125

Subject(s) - cationic polymerization , chlorine , octahedron , crystallography , chemistry , core (optical fiber) , chlorine atom , manganese , crystal structure , stereochemistry , inorganic chemistry , materials science , polymer chemistry , medicinal chemistry , organic chemistry , composite material

Chlorine caged in! The chlorine‐induced assembly of six shuttlecock‐like tetranuclear Mn II building blocks generated in situ based on p ‐ tert ‐butylthiacalix[4]arene and facial anions gave rise to a novel truncated distorted octahedral cationic coordination cage with a μ 5 ‐carbonato‐bridged Mn II 24 core (see figure).

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