Cover Picture: A Convenient and General Palladium‐Catalyzed Carbonylative Coupling for the Synthesis of 2‐Arylbenzoxazinones (Chem. Eur. J. 44/2011) | Zendy

Wu XiaoFeng | Zendy; Schranck Johannes | Zendy; Neumann Helfried | Zendy; Beller Matthias | Zendy

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Cover Picture: A Convenient and General Palladium‐Catalyzed Carbonylative Coupling for the Synthesis of 2‐Arylbenzoxazinones (Chem. Eur. J. 44/2011)

Author(s) -

Wu XiaoFeng,

Schranck Johannes,

Neumann Helfried,

Beller Matthias

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201190215

Subject(s) - carbonylation , domino , palladium , aryl , bromide , catalysis , combinatorial chemistry , chemistry , cover (algebra) , organic chemistry , carbon monoxide , engineering , mechanical engineering , alkyl

A new domino synthesis of 2‐arylbenzoxazinones has been developed by M. Beller and co‐workers. In their Communication on page 12246 ff. , 19 different benzoxazinones were produced in good yields (65–91%) by palladium‐catalyzed carbonylative coupling of commercially available 2‐bromoanilines and (hetero)aryl bromides. The key step of this transformation is the chemoselective carbonylation of the aryl bromide. Moreover, a one‐pot synthesis of 2,3‐diarylquinazolinones was demonstrated exemplarily.

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