Inside Cover: Stepwise Construction of Au 4 Ag 2 Cu 2  Coinage Rings Supported by Linear Tetraphosphine Ligands (Chem. Eur. J. 38/2011) | Zendy

Takemura Yukie | Zendy; Nishida Tomoko | Zendy; Kure Bunsho | Zendy; Nakajima Takayuki | Zendy; Iida Masayasu | Zendy; Tanase Tomoaki | Zendy

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Inside Cover: Stepwise Construction of Au 4 Ag 2 Cu 2 Coinage Rings Supported by Linear Tetraphosphine Ligands (Chem. Eur. J. 38/2011)

Author(s) -

Takemura Yukie,

Nishida Tomoko,

Kure Bunsho,

Nakajima Takayuki,

Iida Masayasu,

Tanase Tomoaki

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201190186

Subject(s) - ring (chemistry) , cover (algebra) , crystallography , ligand (biochemistry) , ion , chemistry , stereochemistry , engineering , receptor , organic chemistry , mechanical engineering , biochemistry

Coinage clusters with octanuclear {Au I 2 Ag I Cu I }2 rings were synthesized with a flexible tetraphosphine ligand, via a dinuclear Au I intermediate. Through a stepwise construction, the Ag I ions in the ring are replaced by Cu I and Au I ions to afford a series of {Au I 2 M I Cu I }2 rings (M=Au I , Ag I , Cu I ), in which the ring shape and size as well as luminous properties are finely modulated by the M element. For more details see the Communication by T. Tanase et al. on page 10528 ff.

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