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Cover Picture: Characterising Lone‐Pair Activity of Lead(II) by 207 Pb Solid‐State NMR Spectroscopy: Coordination Polymers of [N(CN) 2 ] − and [Au(CN) 2 ] − with Terpyridine Ancillary Ligands (Chem. Eur. J. 13/2011)
Author(s) -
Greer Brandon J.,
Michaelis Vladimir K.,
Katz Michael J.,
Leznoff Daniel B.,
Schreckenbach Georg,
Kroeker Scott
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201190060
Subject(s) - lone pair , bifunctional , dication , chemistry , hydrogen bond , nuclear magnetic resonance spectroscopy , supramolecular chemistry , catalysis , crystallography , stereochemistry , combinatorial chemistry , molecule , organic chemistry , crystal structure
Lone‐pair stereochemical activity plays a key structural role in lead(II)‐based coordination polymers. In their Full Paper on page 3609 ff. , S. Kroeker et al. show that 207 Pb solid‐state NMR spectroscopy offers a unique spectroscopic probe linking structural and electronic characteristics with optical properties, providing a predictive tool for materials design.