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Chitosan Bio‐Based Organic–Inorganic Hybrid Aerogel Microspheres
Author(s) -
El Kadib Abdelkrim,
Bousmina Mosto
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201104006
Subject(s) - chitosan , aerogel , supercritical drying , chemical engineering , materials science , adsorption , chitin , hybrid material , microsphere , nanotechnology , chemistry , organic chemistry , engineering
Recently, organic–inorganic hybrid materials have attracted tremendous attention thanks to their outstanding properties, their efficiency, versatility and their promising applications in a broad range of areas at the interface of chemistry and biology. This article deals with a new family of surface‐reactive organic–inorganic hybrid materials built from chitosan microspheres. The gelation of chitosan (a renewable amino carbohydrate obtained by deacetylation of chitin) by pH inversion affords highly dispersed fibrillar networks shaped as self‐standing microspheres. Nanocasting of sol–gel processable monomeric alkoxides inside these natural hydrocolloids and their subsequent CO 2 supercritical drying provide high‐surface‐area organic–inorganic hybrid materials. Examples including chitosan–SiO 2 , chitosan–TiO 2 , chitosan–redox‐clusters and chitosan–clay‐aerogel microspheres are described and discussed on the basis of their textural and structural properties, thermal and chemical stability and their performance in catalysis and adsorption.