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Bonding in a Borylene Complex Investigated by Photoionization and Dissociative Photoionization
Author(s) -
Fischer Kathrin H.,
Schneider Michael,
Fischer Ingo,
Pfaffinger Bernd,
Braunschweig Holger,
Sztáray Bálint,
Bodi Andras
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103993
Subject(s) - photoionization , chemistry , ionization , dissociation (chemistry) , synchrotron radiation , ionization energy , photoemission spectroscopy , spectroscopy , atomic physics , photoionization mode , mass spectrometry , binding energy , x ray photoelectron spectroscopy , photochemistry , physics , ion , organic chemistry , nuclear physics , nuclear magnetic resonance , quantum mechanics , chromatography
The borylene complex [(OC) 5 CrBN(SiMe 3 ) 2 ] has been investigated by using threshold photoelectron–photoion coincidence spectroscopy with synchrotron radiation. The ionization energy of the parent complex and the 0 K appearance energies of the sequential CO loss channels have been determined. The derived bond‐dissociation energies are used to discuss bonding and energetics in this compound.