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A General and Efficient Palladium‐Catalyzed Alkoxycarbonylation of Phenols To Form Esters through In Situ Formed Aryl Nonaflates
Author(s) -
Wu XiaoFeng,
Neumann Helfried,
Beller Matthias
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103797
Subject(s) - palladium , aryl , ferrocene , phenols , organic chemistry , catalysis , in situ , chemistry , combinatorial chemistry , computer science , electrochemistry , alkyl , electrode
Esters made easy! A general and efficient methodology for the palladium‐catalyzed alkoxycarbonylation of in situ formed aryl nonaflates has been developed (see scheme). Both homo‐ and cross‐esterifications are possible. DPPF=1,1′‐bis(diphenylphosphino)ferrocene.
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