An Alkoxido‐Tin‐Substituted Polyoxometalate [(MeO)SnW 5 O 18 ] 3− : The First Member of a New Family of Reactive {SnW 5 } Lindqvist‐Type Anions | Zendy

Kandasamy Balamurugan | Zendy; Wills Corinne | Zendy; McFarlane William | Zendy; Clegg William | Zendy; Harrington Ross W. | Zendy; RodríguezFortea Antonio | Zendy; Poblet Josep M. | Zendy; Bruce Peter G. | Zendy; Errington R. John | Zendy

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An Alkoxido‐Tin‐Substituted Polyoxometalate [(MeO)SnW 5 O 18 ] 3− : The First Member of a New Family of Reactive {SnW 5 } Lindqvist‐Type Anions

Author(s) -

Kandasamy Balamurugan,

Wills Corinne,

McFarlane William,

Clegg William,

Harrington Ross W.,

RodríguezFortea Antonio,

Poblet Josep M.,

Bruce Peter G.,

Errington R. John

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201103544

Subject(s) - polyoxometalate , tin , type (biology) , materials science , crystallography , chemistry , metallurgy , catalysis , organic chemistry , ecology , biology

A SnOW‐bound polyoxometalate : Targeted incorporation of {SnOMe} 3+ into lacunary {W 5 O 18 } 6− has been achieved by hydrolytic self‐assembly. The [(MeO)SnW 5 O 18 ] 3− ion undergoes a reversible one‐electron reduction, shows a large upfield shift of the W ax resonance in the 183 W NMR spectrum and has a calculated HOMO–LUMO gap of 3.5 eV. A wide range of {SnW 5 } derivatives is now accessible by ligand substitution at the Sn centre.

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