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An Approach to the Regioselective Diamination of Conjugated Di‐ and Trienes
Author(s) -
Lishchynskyi Anton,
Muñiz Kilian
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103435
Subject(s) - regioselectivity , hypervalent molecule , reagent , computer science , process (computing) , combinatorial chemistry , chemistry , organic chemistry , programming language , catalysis
It's do or diaminate : The selective diamination of 1,3‐butadienes in the presence of hypervalent iodine reagents has been developed. This oxidation process proceeds with complete selectivity in favor of diamination. Depending on the substrate, it proceeds either with 1,2‐ or 1,4‐regioselectivity (see scheme).