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Metal‐Oxide Nanoparticles with Desired Morphology Inherited from Coordination‐Polymer Precursors
Author(s) -
Zhao Jiao,
Li Mingrun,
Sun Junliang,
Liu Leifeng,
Su Panpan,
Yang Qihua,
Li Can
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103415
Subject(s) - oxide , nanomaterials , nanoparticle , metal , nanotechnology , coordination polymer , perylene , polymer , metal ions in aqueous solution , materials science , scheme (mathematics) , morphology (biology) , metal organic framework , chemistry , molecule , organic chemistry , metallurgy , geology , mathematical analysis , paleontology , mathematics , adsorption , composite material
The “escape‐by‐crafty‐scheme” strategy is an efficient approach to prepare metal‐oxide nanomaterials with desirable morphology and crystal planes inherited from coordination‐polymer nanoparticle precursors, which can be designed and finely tuned by soft chemical assembly of metal ions and organic ligands at the molecular level (see scheme; ptcda=perylene‐3,4,9,10‐tetracarboxylic dianhydride).