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Unsymmetrical p ‐Carborane Backbone as a Linker for Donor–Acceptor Dyads
Author(s) -
Hablot Delphine,
Sutter Alexandra,
Retailleau Pascal,
Ziessel Raymond
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103307
Subject(s) - acceptor , linker , fluorescence , förster resonance energy transfer , photochemistry , carborane , chemistry , energy transfer , nanorod , materials science , nanotechnology , stereochemistry , computer science , chemical physics , optics , physics , condensed matter physics , operating system
Fluorescent nanorods : Donor–acceptor dyads based on novel unsymmetrically disubstituted closo ‐1,12‐dicarbadecaboranes have been prepared in a completely controlled manner by using a three‐step procedure. Dyads with different donor–acceptor spacing were thereby obtained. Efficient energy transfer from the donor to the acceptor was determined in fluid solution at room temperature.