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The Marriage of Organocatalysis with Metal Catalysis: Access to Multisubstituted Chiral 2,5‐Dihydropyrroles by Cascade Iminium/Enamine–Metal Cooperative Catalysis
Author(s) -
Sun Wangsheng,
Zhu Gongming,
Hong Liang,
Wang Rui
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103083
Subject(s) - iminium , enamine , organocatalysis , chemistry , catalysis , combinatorial chemistry , cascade , metal , organic chemistry , enantioselective synthesis , chromatography
Organocatalyst and metal cooperate : The integration of iminium catalysis and enamine–metal cooperative catalysis into a single process facilitates the rapid and controlled production of valuable chiral pyrrolines in excellent diastereo‐ and enantioselectivities (see scheme).