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New Sandwich‐Type Phthalocyaninato–Metal Quintuple‐Decker Complexes
Author(s) -
Wang Hailong,
Kobayashi Nagao,
Jiang Jianzhuang
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103037
Subject(s) - type (biology) , metal , materials science , crystallography , chemistry , geology , metallurgy , paleontology
Quintuple‐decker sandwich : Homoleptic pentakis(2,3,9,10,16,17,23,24‐octa(butyloxy)phthalocyaninato) lanthanide–cadmium quintuple‐decker complexes were isolated and structurally characterized. They represent the first example of sandwich‐type stacked tetrapyrrole–metal complexes with five decks (see figure; the tetrapyrrole molecules are represented by the blue/pink discs, TCB=1,2,4‐trichlorobenzene).