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Enantioselective Intermolecular Carbon–Carbon Bond Formation of Glyoxylate Imines with Allylstannanes Catalyzed by tropos BIPHEP–Gold(I) Complexes with Au–Au Interactions
Author(s) -
Kojima Masafumi,
Mikami Koichi
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201103023
Subject(s) - enantioselective synthesis , intermolecular force , chemistry , catalysis , carbon fibers , stereochemistry , combinatorial chemistry , organic chemistry , medicinal chemistry , computer science , molecule , algorithm , composite number
Interactions act : The enantioselective allylation reaction of glyoxylate imines catalyzed by tropos DM‐BIPHEP–gold(I) complexes with an Au–Au interaction was developed to give a higher enantioselectivity than the atropos DM‐BINAP–gold complexes without an Au–Au interaction (see scheme).