Palladium‐Catalyzed Cascade Cyclization of Ynamides to Azabicycles | Zendy

Greenaway Rebecca L. | Zendy; Campbell Craig D. | Zendy; Holton Oliver T. | Zendy; Russell C. Adam | Zendy; Anderson Edward A. | Zendy

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Palladium‐Catalyzed Cascade Cyclization of Ynamides to Azabicycles

Author(s) -

Greenaway Rebecca L.,

Campbell Craig D.,

Holton Oliver T.,

Russell C. Adam,

Anderson Edward A.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201102880

Subject(s) - cascade , palladium , scope (computer science) , modular design , computer science , scheme (mathematics) , substituent , combinatorial chemistry , chemistry , catalysis , database , organic chemistry , programming language , mathematics , chromatography , mathematical analysis

Cascade reactions : A modular assembly of azabicycles by using a cascade cyclization/Suzuki coupling/6π‐electrocyclization of bromoenynamides is reported (see scheme). The reaction offers a wide substituent scope on the bicyclic aminodiene products, which can be selectively oxidized as a general approach to aromatic azabicycles.

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