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Catalytic CH Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons
Author(s) -
Prechtl Martin H. G.,
Teltewskoi Michael,
Dimitrov Anton,
Kemnitz Erhard,
Braun Thomas
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201102853
Subject(s) - aluminium , catalysis , chemistry , lewis acids and bases , fluoride , nanoscopic scale , amorphous solid , organic chemistry , medicinal chemistry , polymer chemistry , inorganic chemistry , materials science , nanotechnology
Nanoscopic amorphous Lewis acidic aluminium fluorides , such as aluminium chlorofluoride (ACF) and high‐surface aluminium fluoride (HS‐AlF 3 ), are capable of activating CH bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).