Catalytic CH Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons | Zendy

Prechtl Martin H. G. | Zendy; Teltewskoi Michael | Zendy; Dimitrov Anton | Zendy; Kemnitz Erhard | Zendy; Braun Thomas | Zendy

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Catalytic CH Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons

Author(s) -

Prechtl Martin H. G.,

Teltewskoi Michael,

Dimitrov Anton,

Kemnitz Erhard,

Braun Thomas

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201102853

Subject(s) - aluminium , catalysis , chemistry , lewis acids and bases , fluoride , nanoscopic scale , amorphous solid , organic chemistry , medicinal chemistry , polymer chemistry , inorganic chemistry , materials science , nanotechnology

Nanoscopic amorphous Lewis acidic aluminium fluorides , such as aluminium chlorofluoride (ACF) and high‐surface aluminium fluoride (HS‐AlF 3 ), are capable of activating CH bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).

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