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A General Palladium‐Catalyzed Aminocarbonylation of Phenols to Primary Benzamides via In Situ Generation of Aryl Nonaflates
Author(s) -
Wu XiaoFeng,
Neumann Helfried,
Beller Matthias
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201102683
Subject(s) - aryl , palladium , catalysis , primary (astronomy) , phenols , in situ , chemistry , combinatorial chemistry , organic chemistry , physics , alkyl , astronomy
Amides in mind! A novel palladium‐catalyzed amino‐carbonylation of in situ formed aryl nonaflates to give primary amides in moderate to excellent yields has been developed (see scheme).