Premium
Oxidative Trifluoromethylation of Arylboronates with Shelf‐Stable Potassium (Trifluoromethyl)trimethoxyborate
Author(s) -
Khan Bilal A.,
Buba Annette E.,
Gooßen Lukas J.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201102652
Subject(s) - trifluoromethylation , trifluoromethyl , oxidative phosphorylation , chemistry , off the shelf , potassium , organic chemistry , biochemistry , computer science , alkyl , software engineering
Introducing CF 3 : Arylboronic acid pinacol esters are converted into the corresponding benzotrifluorides with the easy‐to‐use one‐component trifluoromethylating reagent potassium (trifluoromethyl)trimethoxyborate, mediated by copper acetate under an oxygen atmosphere (see scheme).