A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents | Zendy

Gotor Raúl | Zendy; Costero Ana M. | Zendy; Gil Salvador | Zendy; Parra Margarita | Zendy; MartínezMáñez Ramón | Zendy; Sancenón Félix | Zendy

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A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents

Author(s) -

Gotor Raúl,

Costero Ana M.,

Gil Salvador,

Parra Margarita,

MartínezMáñez Ramón,

Sancenón Félix

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201102241

Subject(s) - sarin , soman , nerve agent , tabun , chemistry , moiety , chromogenic , derivative (finance) , combinatorial chemistry , stereochemistry , biochemistry , chromatography , acetylcholinesterase , enzyme , business , finance

Lethal‐weapon visualization : A novel triarylmethanol derivative, which is able to colorimetrically distinguish diisopropylfluorophosphate (DFP; a mimic of Sarin and Soman) from other nerve‐agent simulants, is reported (see picture). This probe was designed to contain two reactive sites: an OH group that provides a suitable reactive group for nerve agents and a tert ‐butyldimethylsilylether moiety that is able to react with fluoride, which is a specific byproduct of the phosphorylation of OH by DFP.

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