Buildup of Amphiphilic Molecular Bola from Organic–Inorganic Hybrid Polyoxometalates and Their Vesicle‐Like Supramolecular Assembly | Zendy

Xiao Fengping | Zendy; Misdrahi Mauricio F. | Zendy; Zhang Jin | Zendy; Yin Panchao | Zendy; Hao Jian | Zendy; Lv Chunlin | Zendy; Xiao Zicheng | Zendy; Liu Tianbo | Zendy; Wei Yonggei | Zendy

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Buildup of Amphiphilic Molecular Bola from Organic–Inorganic Hybrid Polyoxometalates and Their Vesicle‐Like Supramolecular Assembly

Author(s) -

Xiao Fengping,

Misdrahi Mauricio F.,

Zhang Jin,

Yin Panchao,

Hao Jian,

Lv Chunlin,

Xiao Zicheng,

Liu Tianbo,

Wei Yonggei

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201101966

Subject(s) - anhydrous , supramolecular chemistry , acetonitrile , amphiphile , alkoxy group , nanoscopic scale , chemistry , materials science , nanotechnology , crystallography , polymer chemistry , molecule , copolymer , organic chemistry , alkyl , polymer

Bisarylamines with o ‐alkoxy substituents [ o ‐NH 2 ‐C 6 H 4 ‐O(CH 2 ) 1/2/3 ] 2 react with [ n Bu 4 N] 4 [ α ‐Mo 8 O 26 ] in anhydrous acetonitrile in the presence of N , N′ ‐dicyclohexylcarbodiimide (DCC) to form a series of nanoscale molecular bola, bisorganoimido‐bridged hexamolybdates with flexible alterable lengths, in which two hexamolybdate cages are connected by the bisarylimido linkers (see scheme).

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