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Nickel‐Catalyzed CP Cross‐Coupling by CCN Bond Cleavage
Author(s) -
Sun Meng,
Zhang HongYu,
Han Qi,
Yang Kuo,
Yang ShangDong
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101930
Subject(s) - nickel , bond cleavage , catalysis , cleavage (geology) , coupling (piping) , coupling reaction , chemistry , denticity , combinatorial chemistry , crystallography , materials science , organic chemistry , metallurgy , crystal structure , composite material , fracture (geology)
Prosperous coupling : A nickel‐catalyzed CP cross‐coupling reaction with Me 3 SiPPh 2 by carbon–cyano bond cleavage has been developed. This method is characterized by its simplicity and wide application to the synthesis of various monophosphorus and P,N bidentate ligands (see scheme).