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Palladium‐Catalyzed CH Bond Functionalization of a Metal–Organic Framework (MOF): Mild, Selective, and Efficient
Author(s) -
Dröge Thomas,
Notzon Andreas,
Fröhlich Roland,
Glorius Frank
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101850
Subject(s) - palladium , regioselectivity , surface modification , catalysis , metal organic framework , chemistry , combinatorial chemistry , organic chemistry , adsorption
Mild‐mannered MOFs : A selective and efficient palladium‐catalyzed CH phenylation of a UMCM‐1‐type metal–organic framework (MOF) under mild conditions is reported. This highly regioselective postsynthetic modification obviates the need for a pre‐existing classical functional group at the reaction site (see scheme). The concept of site‐specific CH activation could potentially be extended to many classes of MOF structures.