Cu I /H 2 /NaOH‐Catalyzed Cross‐Coupling of Two Different Alcohols for Carbon–Carbon Bond Formation: “Borrowing Hydrogen”? | Zendy

Miura Takashi | Zendy; Kose Osamu | Zendy; Li Feng | Zendy; Kai Sun | Zendy; Saito Susumu | Zendy

Premium

Cu I /H 2 /NaOH‐Catalyzed Cross‐Coupling of Two Different Alcohols for Carbon–Carbon Bond Formation: “Borrowing Hydrogen”?

Author(s) -

Miura Takashi,

Kose Osamu,

Li Feng,

Kai Sun,

Saito Susumu

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201101752

Subject(s) - carbon fibers , catalysis , hydrogen , coupling (piping) , carbon chain , chemistry , coupling reaction , reinforced carbon–carbon , medicinal chemistry , organic chemistry , materials science , composite number , composite material , metallurgy

Not borrowed : A new method was developed for the cross‐coupling of two different alcohols (see scheme). This carbon–carbon bond formation was realized by using a small amount of CuBr (0.05–0.2 mol %) and NaOH (4–20 mol %) in the presence of H 2 (1 atm), and provides an alternative procedure for longer‐chain alcohols. The catalytic cycle was different from those reported to date for the Guerbet reaction involving “borrowing hydrogen”.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research